SHRIMP U–Pb dating of coesite-bearing zircon from the ultrahigh-pressure metamorphic rocks, Sulu terrane, east China

This paper provides further evidence for the ongoing discussion as to whether the Dabie UHPM belt formed in Triassic or Palaeozoic time, and whether the Sulu UHPM belt formed in Triassic or Neoproterozoic time. Combined use of laser Raman spectrometer (LR), cathodoluminescence imaging (CL), and ion probe U–Pb in‐situ dating (SHRIMP) provided accurate ages of UHPM from rocks collected from Weihai, NE Sulu UHPM belt. LR was used to identify coesite and other UHP minerals as inclusions in zircon separates from an amphibolized peridotite and an eclogite. CL was used to examine the zoning structure of these zircon, and SHRIMP dating was performed on specific spots on zircon to obtain ages of different geological events. An age of 221 ± 12 Ma was obtained for coesite‐bearing zircon from the amphibolized peridotite; an age of 228 ± 29 Ma for eclogite was obtained from the lower intercept of a concordia plot. These ages are interpreted as the time of UHPM in the Weihai region. Ultramafic rocks to the east of Weihai yield a magmatic age at 581 ± 44 Ma. The zircon in the ultramafic rocks possibly also records a thermal event at c. 400 Ma, but no independent geological evidence for this event has been found. The eclogite protolith formed in the Middle Proterozoic (1821 ± 19 Ma), which is similar to the age of country rock gneisses of 1847–1744 Ma. The new geochronological data confirm that UHPM occurred in the Triassic in the Sulu area when subduction took the ultramafic body and the eclogite protolith, together with the adjacent supracrustal rocks, to mantle depths.     

Journey‐to‐Work Patterns in the Age of Sprawl: Evidence from Two Midsize Southern Metropolitan Areas*

Among others, one commonly identified negative consequence of urban sprawl is an increase in the length of the journey to work. However, there has been more discussion of this than serious scrutiny, hence the relationship between urban sprawl and commuting patterns, especially at the intraurban level, remains unclear. Using the 2000 Census Transportation Planning Package (CTPP) data for two Southeastern metropolitan areas, this research investigates the extent to which workers living in sprawl areas commute farther to work than those living in higher density areas. The analysis of variance confirms that workers commuting from sprawl areas to urban areas experience a longer commute in terms of time as well as mileage, though this varies when workplace and home locations are taken into account. However, multivariate statistical results suggest that there are limits to the utility of sprawl as a predictor of travel behavior compared to workers' socioeconomic characteristics, as other factors appear to be equally or more important.     

Estimating groundwater storage changes in the Mississippi River basin (USA) using GRACE

Based on satellite observations of Earth’s time variable gravity field from the Gravity Recovery and Climate Experiment (GRACE), it is possible to derive variations in terrestrial water storage, which includes groundwater, soil moisture, and snow. Given auxiliary information on the latter two, one can estimate groundwater storage variations. GRACE may be the only hope for groundwater depletion assessments in data-poor regions of the world. In this study, soil moisture and snow were simulated by the Global Land Data Assimilation System (GLDAS) and used to isolate groundwater storage anomalies from GRACE water storage data for the Mississippi River basin and its four major sub-basins. Results were evaluated using water level records from 58 wells set in the unconfined aquifers of the basin. Uncertainty in the technique was also assessed. The GRACE-GLDAS estimates compared favorably with the well based time series for the Mississippi River basin and the two sub-basins that are larger than 900,000 km². The technique performed poorly for the two sub-basins that have areas of approximately 500,000 km². Continuing enhancement of the GRACE processing methods is likely to improve the skill of the technique in the future, while also increasing the temporal resolution.     

Controls on dissolved inorganic carbon and δC in cave waters from DeSoto Caverns: Implications for speleothem δC assessments

Unraveling the factors controlling the carbon chemistry and transport of carbon within extant karst systems has important implications concerning the assessment of time-series δ¹³C records of speleothems. Here we report the results of a 3-year study of total dissolved inorganic carbon [DIC] and δ¹³C_DIC from cave waters at DeSoto Caverns (Southeastern USA) that offer valuable insight on carbon transport and the accompanied isotope fractionations from end-member sources to speleothems.[DIC] and δ¹³C_DIC values of cave waters range from 0.2 to 6.0 mM and 2.7 to −12.9 (‰ VPDB), respectively. [DIC] and δ¹³C_DIC of “seasonal drips” show seasonal, albeit noisy, variability and are inversely related (δ¹³C_DIC = −2.49[DIC] + 0.64, r² = 0.84). A shallow pool fed by multiple drips shows a bimodal δ¹³C_DIC distribution with an isotopically heavier mode during winter (−4‰ to −5‰ VPDB) relative to summer months (−9‰ to −10‰ VPDB). A multi-year trend of decreasing water availability during the study period is not reflected in a response of cave water carbon chemistry suggesting that rainfall amount may not be a significant controlling factor of the carbon chemistry. Coupled cave air winter ventilation/summer stagnation and varying CO₂ fluxes through the soil horizon and epikarst exert the strongest influence on seasonal [DIC] and δ¹³C_DIC variability. Measured values of high [DIC] and low δ¹³C_DIC from cave waters collected during the summer/early fall closely approximate isotopic equilibrium conditions. Conversely, low [DIC] and high δ¹³C_DIC values during winter/early months indicate kinetically enhanced isotopic fractionations within the cave waters. The kinetically enhanced isotopic fractionation of partitioned between degassed CO₂ and precipitated CaCO₃(1000lnα_{[(CO2-HCO3)+(CaCO3(AR)-HCO3)]/2}) is greater by about a factor of two (−6.7 ± 0.3‰) relative to the same isotopic fractionation under equilibrium conditions (−3.1‰).On the basis of ¹⁴C mass balance and paired ¹⁴C-U/Th measurements we estimate that on average about ∼23% of C delivered annually by the drips to the aragonite stalagmites is derived from ¹⁴C-dead dolomite cap while the remainder of ∼77% is derived from ¹⁴C-live biomass. δ¹³C measurements of aragonite (n = 12) sampled from the tips of active speleothems during the summer months are consistent with theoretical aragonite δ¹³C values calculated using the shallow pool summer/early fall data thus confirming the δ¹³C seasonality in both drips and coeval aragonite. δ¹³C values of an active stalagmite section spanning the last 200 years show a normal distribution with a mean of −7.1 ± 1.2‰ (n = 81) and a mode of −7‰ to −8‰ that are statistically indistinguishable from the annual mean and mode of all dripwaters. Thus secular time-series δ¹³C records of stalagmites at DeSoto Caverns with resolving power >10⁻¹ year will likely carry the imprints of drip annual means that record climate-driven δ¹³C seasonal biases.     

Spectroscopic Observations of the 2011 Draconids Meteor Shower

Some past October Draconid shower meteoroids fell apart in a spray of fragments at the end of their trajectory before slowing down, from which it was concluded that these were among the most fragile meteoroids known. In those instances, the dust could not be reliably traced to a particular return of the parent comet 21P/Giaconini-Zinner. On October 8th, 2011, Earth was predicted to transverse the 1900 A.D. dust ejecta of the comet. In 1900, the comet’s perihelion distance first moved significantly inwards to the Sun and ejection conditions could have been unusual. An airborne observing campaign was organized, with several teams contributing imaging and spectrographic cameras to study the manner in which these meteoroids released the volatile element sodium during the ablation process in the Earth’s atmosphere. IMCCE, ESA, and the SETI Institute contributed spectrographic cameras based on low-light WATEC 902H2 Ultimate, low-light LCC1, and GenII XX1332 image intensified cameras. An outburst was observed, much as predicted. Despite a lack of bright meteors, a total of 15 Draconid spectra were recorded. All show evidence of an early release of sodium. The loss of sodium was observed to coincide with the formation of a distinct wake of fragments. The observations show that 21P/Giacobini-Zinner ejected fragile meteoroids during the return in 1900. Those grains may have lost some sodium even before impacting Earth.     

Application of kinematic wave theory for predicting flash flood hazards on coupled alluvial fan–piedmont plain landforms

A rainstorm that caused a severe flash flood on the piedmont plain at the toe positions of two alluvial fans located to the west of the Organ Mountains in Dona Ana County, New Mexico, USA, is analysed. The space–time distributions of rainfall are evaluated from the Next Generation Weather Radar (NEXRAD) and overland flow is modelled as kinematic wave. The spatial distribution of rainfall shows a topographic control. The greatest rainfall depth, duration, and intensity occurred at the higher elevation mountain slopes and decreased with decreasing elevation from the alluvial fans to the piedmont plain. The alluvial fan–piedmont plain system is modelled by coupling divergent and rectangular overland flow planes. Explicit finite difference approximations, hybridized with the analytical method of characteristics, are made to the kinematic wave equations to account for the spatial and temporal distribution of the rainfall and variable boundary conditions. Simulation results indicate that sheet‐flow floodwater elevations rise (1) in a nonlinear fashion from the apex to toe positions of the alluvial fans, and (2) near linearly from the toe positions of the alluvial fans onto the piedmont plains with the formation of kinematic shocks near the middle to the upstream end of the plane at times between the initiation of the rainstorm and the time of concentration of the plane. Thus, the maximum flooding occurs at the middle or upstream sections of the piedmont plains regardless of the pattern of space–time variability of rainfall. These results are in agreement with observed geomorphologic features suggesting that piedmont plains are naturally flood‐prone areas. This case study demonstrates that flood hazards on piedmont plains can exceed those on alluvial fans. The models presented in this study suggest that the flood hazard zones on coupled alluvial fan–piedmont plain landforms should be delineated transverse to the flow directions, as opposed to the flood hazard zones with boundaries in the longitudinal direction of the axis of an alluvial fan. Copyright © 2003 John Wiley & Sons, Ltd.     

3D seismic technology: the geological 'Hubble'

The proliferation of three‐dimensional (3D) seismic technology is one of the most exciting developments in the Earth Sciences over the past century. 3D reflection seismic data provide interpreters with the ability to map structures and stratigraphic features in 3D detail to a resolution of a few tens of metres over thousands of square kilometres. It is a geological ‘Hubble’, whose resolving power has already yielded some fascinating (and surprising) insights and will continue to provide a major stimulus for research into geological processes and products for many decades to come. Academic and other research institutions have a major role to play in the use of this data by exploiting the enormous volume of geological information contained in 3D seismic surveys. This paper reviews some of the recent advances in basin analysis made using the medium of 3D seismic data, focusing on the fields of structural and sedimentary geology, fluid–rock interactions and igneous geology. It is noted that the increased resolution of the 3D seismic method provided the essential catalyst necessary to stimulate novel observations and discover new geological structures such as mud diapir feeders, km‐long gas blow‐out pipes, giant pockmarks and sandstone intrusions, and to capture the spatial variability of diagenetic fronts. The UKs first impact crater was also discovered using 3D seismic data. The potential for future developments in this field of geophysical interpretation is considerable, and we anticipate that new discoveries will be made in many years to come.